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Copper (I) coordination networks synthesized with solid-solid reactions
(University of Missouri--Columbia, 2008)
The use of solid-solid reactions in the development of one-, two-, and three dimensional Cu(I) coordination networks are discussed. The solid-solid reactions were monitored by a variety of instrumental techniques to achieve ...
Ammonia elimination from protonated nucleobases
(University of Missouri--Columbia, 2007)
The dediazoniations of the diazonium ion 1 of 4-aminopyrimidine and of the tautomeric cytosinediazonium ions 2 and 3 are facile and result in the formations of cations 4, 5, and 6. The pyrimidine ring-opening of 4, 5 and ...
Investigation of CO2 capture systems, Lewis acid-base pairs, and oscillating reactions with electronic structure theory and kinetics-based approaches
(University of Missouri--Columbia, 2020)
the capture of CO2 by small alkylamines. The quality of that discussion was tested directly with the work described in Chapter 2. The work that led to Chapter 2 was an enormous learning experience; it was amazing to see all the pieces of the complicated multi...
High valent uranium dioxo and imido complexes : synthesis and structure
(University of Missouri--Columbia, 2008)
. Whereas high oxidation state ions dominate environmental speciation, the corresponding high-valent organometallics are rare. These hexa- and pentavalent ions are often stabilized by the isoelectronic oxo or imido ligands, which result in robust molecular...